李立军
一、个人简介
李立军, 男，教授，硕士生导师。1969年3月出生，河北省定州人，兰州大学博士，中科院北京化学所、日本京都大学、美国桥港大学访问学者。迄今为止，在Green Chem., Org. Lett., Chem. Commun., Adv. Synth. Catal., J. Org. Chem.等杂志上发表110多篇，其中SCI收录论文59篇，EI收录9篇，先后主持河北省自然科学基金4项、河北省科技攻关计划项目1项，参与国家自然科学基金、省自然科学基金等科研项目多项。
二、主讲课程及研究方向
1. 主讲课程：有机化学，有机合成化学，Advanced Organic Chemistry等。
2. 研究方向：有机合成化学；配位化学；有机催化。
三、代表性论文
1. Changyou Guo, Jingyi Chen, Lijun Li,* Xin Gu, Qinqin Yan,* Kai Sun*, and Zejiang Li*, Visible light-initiated silylation cyclization of alkynes to access diverse silylated fused cycles. Adv. Syn. Catal., 2025, DOI: 10.1002/adsc.202500245.
2. Changyou Guo, Lijun Li,* Qinqin Yan, Jingyi Chen, Zhong-Quan Liu,* Quan-Xin Li, Shao-Fei Ni,* and Zejiang Li.* Radical three-component nitro spiro-cyclization of unsaturated sulfonamides/amides to access NO2-featured 4-azaspiro[4.5]decanes. Org. Lett. 2024, 26(15), 3069-3074.
3. Hongxun Zhou, Lijun Li,* Qinqin Yan, Jinyue Ma, Ying Wang, Yongjun Gao, Zhong-Quan Liu* and Zejiang Li.* Metal-free radical bicyclization/chloroalkylarylation of 1,6-enynes with chloroalkanes. Chem. Comm., 2024, 60(29), 3938-3941.
4. Changyou Guo, Lijun Li,* Qinqin Yan, Hongxun Zhou, Zhong-Quan Liu,* and Zejiang Li,* Photoinduced Tandem Cyanomethylation/Cyclization of Unsaturated Compounds: Access to Cyanomethylated 7- or 5-Membered N-Heterocycles, J. Org. Chem., 2023, 88, 12141- 12149.
5. Yang Li, Lijun Li,* Changyou Guo, Qinqin Yan, Hongxun Zhou, Ying Wang, Zhong-Quan Liu,* and Zejiang Li,* Nitro-Spirocyclization of Biaryl Ynones with tert-Butyl Nitrite: Access to NO2-Substituted Spiro[5,5]trienones. J. Org. Chem., 2023, 88, 4854−4862.
6. Shiliu Chen, Qinqin Yan, Jie Fan, Changyou Guo, Lijun Li,* Zhong-Quan Liu* and Zejiang Li.* Photo-induced spirocyclization of biaryl ynones with ammonium thiocyanate: access to thiocyanate-featured spiro[5,5]trienones. Green Chem., 2023, 25, 153-160.
7. Yiming Li, Jiaqing Liu, Ke Shui, Fan Xie, Xuan Li, Yi Lin, Zehua Zhou, Qing Zhang, Fengqi Guo, Lijun Li,* Jinchong Xiao,* Meng Wang,* and Chang-Qi Ma.* Synthesis of crown ether end-capped PM6 copolymers with 2 tunable molecular weight for organic solar cells. Macromolecules, 2023, 56(16), 6276-6289.
8. Jie Fan, Qinqin Yan, Huaqing Liu, Lijun Li,* Zhong-Quan Liu* and Zejiang Li.* Photo- promoted cascade cyclization of aryl alkynes: access to thiocyanate/trifluoromethylthio- containing quinolino[2,1-b] quinazolinones. New J. Chem., 2023, 47, 20713-20717.
9. Shiliu Chen, Qinqin Yan, Jie Fan, Lijun Li*, Zhong-Quan Liu*, Zejiang Li*, Photoinduced Tandem Cyclization of Alkynes with Phenylsulfinic Acids: Access to Sulfone-Substituted Dioxodibenzothiazepines or Dibenzazepines. Synlett, 2022, 33, 1733–1738.
10. Yang Li, Lijun Li*, Qinqin Yan, Yingming Ren, Xuan Li, Fan, Zhong-Quan Liu*, Zejiang Li*, Free-radical-involved trifluoromethylthiolation cyclization of alkenes to access SCF3-substituted indolo[2,1-a]isoquinolines. Synlett, 2022, 33, 1938–1942.
11. Yingming Ren, Qinqin Yan, Yang Li, Yongjun Gao, Jincan Zhao, Lijun Li,* Zhong-Quan Liu,* and Zejiang Li*, Free Radical Promoted Trifluoromethylthiolation of Alkynes to Access SCF3-Containing Dibenzazepines or Dioxodibenzothiazepines, J. Org. Chem. 2022, 87, 8773−8781.
12. Shiliu Chen, Qinqin Yan, Jie Fan, Yongjun Gao, Xiulong Yang, Lijun Li,* Zhongquan Liu* and Zejiang Li*, Photoinduced cascade cyclization of alkynes with NH4SCN: access to SCN-containing dibenzazepines or dioxodibenzothiazepines. Green Chem., 2022, 24, 4742-4747.
13. Yingming Ren, Yaxin Ge, Qinqin Yan, Shiliu Chen, Yang Li, Lijun Li, Zhong-Quan Liu* Zejiang Li,* Free radical-promoted monochloroalkylarylation of alkenes with chloralkanes, J, Org. Chem., 2021, 86, 12460-12466.
14. Yingming Ren, Yaxin Ge, Qinqin Yan,* Yunfei Tian,* Jilai Wu, Yujie Yang, Lijun Li, Zejiang Li,* Iron-Mediated Radical Nitro-Halogenation Reactions of Enynes with tert-Butyl Nitrite, Synlett, 2021, 32(12), 1192-1196.
15. Jin-Min Liu, Ya-Bin Ren, Hao-Yu Xu, Li-Jun Li, Ya-Juan Mu, Jian-Long Du,* Construction of a stable Zn(II)-MOF based on mixed ligand strategy for fluorescence detection of antibiotics and Fe3+ ions. Inorganica Chimica Acta, 2021, 527, 120583.
16. Zhaokuo Zhang, Ziwei Yang, Yujing Wu, Zhen Yuan, Jianlong Du, Lijun Li*. Reduced amino acid Schiff base containing ruthenium (III) complexes: Synthesis, characterization, DNA interaction, and in vitro cytotoxicity. J. Biochem. Mol. Toxicol. 2020, 34:e22510. DOI: 10.1002/jbt.22510.
17. Hui Chang, Wenting Mao, Yingying Duan, Wanning Zhang, Chao Zhou, Lu Han*, Lijun Li*, and Shunai Che* Highly Ordered AIEgen Directed Silica Hybrid Mesostructures and Their Light-Emitting Behaviours. J. Mater. Chem. C, 2019, 7, 346-353.
18. Li-Qiang Zuo, Teng-Fei Zhang, Zhao-Kuo Zhang, Jin-Xin Hou, Guo-Jun Liu, Jian-Long Du, Li-Jun Li*. A 3D binuclear salen-based multifunctional MOF: Degradation of MO dye and highly selective sensing of Fe3+. Inorg. Chem. Commun. 2019, 99, 113-118.
19. Jin-Xin Hou, Ju-Ping Gao, Jie Liu, Xu Jing, Li-Jun Li, Jian-Long Du*. Highly selective and sensitive detection of Pb2+ and UO22+ ions based on a carboxyl-functionalized Zn(II)-MOF platform. DYES PIGMENTS, 2019, 160, 159-164.
20. Jie Liu, Xiao-Ying Zhang, Jin-Xin Hou, Jin-Min Liu, Xu Jing, Li-Jun Li, Jian-Long Du*, Functionalized Mn(II)-MOF based on host-guest interaction for selective and rapid capture of Congo red from water. J. Solid State Chem. 2019, 270, 697-704.
四、科研项目
1. 纳米孔催化材料的制备与表征(编号05215104),河北省科技攻关计划项目,(2006.1-2008.12，主持）
2. 功能化多孔性配位聚合物的制备(B2007000152)，河北省自然科学基金,（2007.1-2009.12，主持）
3. 多孔手性Salen配位聚合物催化材料的制备与性能(B2010000223)，河北省自然科学基金,（2010.1-2012.12，主持）
4. 氨基酸Schiff碱衍生物及其铂配合物的合成与抗肿瘤活性研究（B2014201174），河北省自然科学基金,（2014.1-2016.12，主持）
5. 光催化硅中心自由基参与的双官能团化或串联合环反应(B2022201059)，河北省自然科学基金,（2022.1-2024.12，主持）
